長波紫外線で青色から茶色に変化するジルコン

Zircon that changes from blue to brown when exposed to long-wave ultraviolet light

good morning.

This is Nori-chan, a GTJ staff member.

I also want to change and evolve.

In early October 2024, we suddenly introduced several zircons that appeared to be a mixture of bright blue and green.

At first, he said, "I bought it because I was attracted by its bright, mysterious and beautiful color." However, he discovered that it underwent an interesting change when exposed to UV light during photography, a process that is carried out before it is sold as a product. This is the change in the color of the base, which is the subject of this article, and is commonly known as the "tenebressence effect."

Tenebrescence (photochromism) is an optical effect in which the color of a mineral changes as it absorbs long-wave ultraviolet light. A typical example is hackmanite, which absorbs long-wave ultraviolet light and turns deep purple, then gradually returns to its original color. (※1)

This time, I will write about blue zircon that I purchased a while ago, and it is not a specialized article about mineralogy or the like, but rather an article with the purpose of observing minerals, like an experiment that anyone can do if they have the equipment.

This zircon was one of several introduced during the live show. The zircon's body color is a pale brownish blue. (※2)

UV light is applied. It is irradiated for about 1 minute during live performances. This UV light is designed to block visible light, so you can feel a significant change even after 10 seconds.

After about a minute of exposure to long-wave UV rays, the color has turned dark brown. The blue has disappeared quite clearly, and the brown has become more prominent.

It feels like the zircon, which is brownish blue (light blue) with a metallic luster, has changed color to a very solid brown zircon. The color change is more noticeable than I expected, but because the original color contains a blue tint, the difference in color change before and after is more clearly visible.

There is currently no mention of "tenebressence" in the EGL sorting. However, since there have been so many changes, I took the opportunity to request an identification certificate from the Japan-Germany Gemological Institute.

The image above is the test result. In the remarks column, it says "Tenebrescence (photochromism) observed." Pieces with too little change are not recognized as tenebresence, but I think that this lot has changed to a degree that is recognized as tenebresence. (※3)
This raises a question: "Will other blue zircons change color?" I decided to try exposing some blue zircons I had on hand to long-wave ultraviolet light.
This is a vintage zircon with a slightly stronger blue color. Since it is blue, it is a piece made by heating Cambodian zircon at 800-1000℃.
If you expose it to long-wave UV light for about 30 seconds...
It's hard to say that it has changed, but I was able to sense a slight difference in color. It feels like it has absorbed long-wave ultraviolet light and become slightly brownish. However, at this level, it might be more accurate to say that it has "become duller than changed." Even if I took it to the Japan-Germany Gemological Institute, there is a high chance that it would not be recognized as tenebresence. I have seven blue zircons on hand, and I was able to observe some kind of change in all but one.
Basically, the color just becomes duller, but the last lot we purchased had a color change that was quite distinct between blue and brown, so it may be a little unusual to get to this point.
Currently, there are only a few commercially available zircons that show the clear color change that can be called the tenebrescence effect, but it seems likely that more interesting zircons will be discovered in the future.
*1 This time we will not explain the principle, but only the visual changes.
*2 This zircon is a privately owned reference stone and is not for sale.
*3 When identifying such minerals, if you ask "Do you recognize tenebrescence? If so, please provide photos of the before and after changes," they will also provide photos (additional charge applies).
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